Poly[di(2-thiophenyl)carborane]s: conducting polymers with high electrochemical and thermal resistance.
نویسندگان
چکیده
The synthesis, X-ray structure and electropolymerization of three new carbon-carbon linked di(2-thiophenyl)carboranes (, and ) are reported; the resulting polymers bearing icosahedral ortho-, meta- or para-carborane clusters show high thermal and electrochemical stabilities in comparison with unsubstituted polythiophene; the ortho-carborane-containing polymer has the highest conductivity of the new materials.
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عنوان ژورنال:
- Chemical communications
دوره 42 شماره
صفحات -
تاریخ انتشار 2007